Integrated sensor device and measuring system using the same

ABSTRACT

An integrated sensor device having a structure suited for mass production despite of a short lifetime and automatically replaceable, and a measuring system realizing a continuous monitoring at a low cost by using the integrated sensor device are disclosed. The integrated sensor device is constructed into a signal integrated circuit device comprising a sensor unit ( 6 ) for measuring a change in the quantity or concentration of a substance; a control unit ( 7 ) for processing a signal representing the measurement result; and an antenna unit ( 10 ) for transmitting the processed signal to the outside and for receiving an energy necessary for the transmission and the operations of the sensor unit ( 6 ) and the control unit ( 7 ).

FIELD OF THE INVENTION

[0001] The present invention relates to an integrated sensor device for measuring a change in quantity of a substance to be measured, and also relates to a measuring system using the device.

BACKGROUND ART

[0002] Various sensors used for detecting (or measuring) quantity (including concentration) of a substance have been provided. For example, an integrated ion sensor that has an ion sensible membrane, a signal processing circuit and a reference electrode mounted on one-chip is disclosed in Japanese Patent Laid-Open Publication No.4-363651. This integrated ion sensor has a plurality of connection terminals for supplying power and collecting measurement results through lines connected to the terminals.

[0003] Also, the sensors disclosed in Japanese Patent Laid-Open Publication No. 6-42983 and Japanese Patent Laid-Open Publication No. 11-311615 are constructed to transmit or receive the measurement result and energy for driving the sensor by wireless between the sensor and outside devices.

[0004] Generally the lifetime of such sensors is finite. That is, measuring performance of a sensor is deteriorated gradually through being exposed in circumferential environment or the like. Particularly, a chemical sensor or a bio-sensor which can be used not for measurement of temperature or pressure but for detection of substance is generally poor in stability for a long time. Accordingly, it is necessary to replace the deteriorated sensor by a new one and the shorter a lifetime of the sensor is, the more frequently the replacement must be performed. Japanese Patent Laid-Open Publication No. 9-297832 discloses a measuring instrument that may automatically decide a lifetime of the sensor to inform the necessity of replacement to a worker because it is troublesome for the worker to judge the deterioration of the sensor.

[0005] However, there are problems in the conventional sensors as follows:

[0006] As described in Japanese Patent Laid-Open Publication No. 6-42983, a sensor having assembly of a plurality of boards, on which electrical circuits are arranged for processing the measurement signal, may complicate wiring and large. Generally the production cost of such sensor becomes higher.

[0007] Also, even if a sensor is constructed into a single chip as shown in Japanese Patent Laid-Open Publication No. 4-363651, the sensor is connected to outside devices by wires, thus there are problems in cost or reliability, such as troublesome in replacement of sensor, requirement of manual works, high cost for replacement of parts, and less reliability of connection by connectors.

[0008] Further, as described in Japanese Patent Laid-Open Publication No.9-297832, when necessity of replacement of sensor is informed to a worker, there is no problem if the measuring instrument is used only where the worker stays. However, when measurement should be done in absence of worker nearby, a worker cannot know even if necessity of replacement of sensor may be indicated. Also, even if it can be informed by the other methods, the worker has to come to the measuring instrument to be replaced, resulting in problems of cost and reliability of connectors because of such manual works. For example, if an object to be measured is dangerous medicine, the replacement of sensors would be more troublesome and it would cost high.

[0009] Also, as common to every cases, when the measuring instrument is arranged in place where a hand cannot reach or it is very difficult to replace the instrument by hand, for example, when it is used at deep places such as underground and underwater, inside of pipe, outer space or the like, the measuring instrument could not be used at the time when the lifetime of the sensor terminates, according to the methods as mentioned above. This is fatal in detection or measurement.

[0010] On the other hand, many investments, long term and great risk would be required for development of a sensor device that has a long lifetime and may not be necessary for replacement for a long time, specifically for development of a sensible membrane. Therefore, nowadays the cheaper sensors that can be manufactured by current technology despite of a short lifetime have been used.

DISCLOSURE OF INVENTION

[0011] An object of the present invention is to provide an integrated sensor device which is economical due to sensor structure integrated into a single chip, in which the lifetime of each sensor is not so long but which is suited for mass production. Another object of the present invention is to provide a measuring system which realizing continuous long term measurement without manual intervention by automatically replacing a degraded sensor to new one in measurement with such integrated sensor device.

[0012] An integrated sensor device of the present invention is constructed into a single integrated circuit device comprising a detection unit that has an organic membrane, characteristics of which are changed through contact with gas or liquid containing substance to be measured, and a converter for converting the change of the characteristics to electric signal; a control unit for processing the signal representing the measurement result from the detection unit; and an antenna unit for transmitting the signal processed by the control unit to outside and for receiving energy necessary for the transmission and operations of the detection and control units from the outside.

[0013] An integrated sensor device according to an embodiment of the present invention is constructed into a single integrated circuit device comprising a detection unit that consists of an ion sensible FET device for measuring pH concentration in aqueous solution and a reference electrode; a thermal sensor for correcting measurement result of the detection unit; a control unit for processing a signal representing measurement result from the detection unit; and an antenna unit for transmitting the signal processed by the control unit to outside and for receiving energy necessary for the transmission and operations of the detection and control units from the outside.

[0014] According to a preferable embodiment, the control unit has memory for pre-storing correcting information to correct the measurement result of the detection unit, and in operation the control unit corrects the measurement result in accordance with the correcting information and transmits the corrected measurement result from the antenna unit.

[0015] Also, there is provided a reading device which comprises an antenna unit for receiving the measurement result (or corrected measurement result) transmitted from the integrated sensor device of the present invention and for transmitting energy to be supplied to the integrated sensor device; and a display unit for displaying information on the measurement result received from the integrated sensor device through the antenna unit.

[0016] A measuring system of the present invention comprises the integrated sensor device as mentioned above; a container for storing a plurality of the integrated sensor devices; an actuator for actuating predetermined number of the integrated sensor devices stored in the container to be usable and for removing the deteriorated integrated sensor device; a controller for controlling operation of the actuator based on decision of whether performance of the integrated sensor device is deteriorated or predetermined time for use terminates; and an antenna unit for receiving the measurement result transmitted from the integrated sensor device in use and for transmitting energy to be supplied to the integrated sensor device.

[0017] In a measuring system of the present invention, a plurality of containers, each of which stores the integrated sensor device one by one, may also be used. Preferably, the container has a seal to prevent invasion of gas or liquid from outside, or has absorbent inside to absorb a substance that deteriorates the integrated sensor device.

[0018] As such container, for example, a container, each of which has a lid partly or wholly made by thin membrane, for sealing the integrated sensor device one by one inside together with gas or liquid to maintain the integrated sensor device in stability, may preferably be used.

[0019] According to the present invention, there is also provided a container device which comprises storage for storing a plurality of the integrated sensor devices in seal, or the integrated sensor device in seal one by one.

[0020] According to the integrated sensor device of the present invention, the measurement result of the detection unit is processed by the control unit to be transmitted to the outside through the antenna unit, and also the energy necessary for the transmission and the operations of the detection unit and the control unit is supplied through the antenna unit. That is, the transmission of the measurement result and the energy to be supplied are performed by wireless. Therefore, even if the measuring point is changed, it is possible to correspond thereto flexibly. Also, since the integrated sensor device is constructed into a single integrated circuit device comprising a detection unit, a control unit and an antenna unit, it has small size and the wiring to connect each unit incorporated, which is suitable for mass production.

[0021] As the integrated sensor device of the present invention is constructed into a single chip, the cost can be reduced, and further it realizes the transmission and the supply of energy by wireless, resulting in no problem in reliability of connection and easy replacement of the sensor device.

[0022] In the measuring system of the present invention, the actuator may actuate the predetermined number of the integrated sensor devices stored in the container to be usable. The transmitting and receiving unit may receive the measurement result transmitted from the integrated sensor device in use and transmit the energy to be supplied to the integrated sensor device. If the performance of the integrated sensor device in use deteriorated, the controller may decide the deterioration of performance to control the operation of the actuator is controlled so that the deteriorated integrated sensor device is removed and an unused integrated sensor device is caused to be usable state. That is, the deteriorated integrated sensor device is automatically replaced by a new one. Therefore, manual operation is not necessary for the replacement of sensor device and the sensor device having short lifetime can be used for replacement promptly, thus it is possible to realize the continuous measurement for a long time without use of the sensor device having long lifetime because a hand is

[0023] The measuring system of the present invention can be applied even in a place where the manual operation of replacement is difficult or impossible.

[0024] Further, the storage of the integrated sensor device in the container can realize the all-purpose measuring system permitting to use many kinds and wide range of sensor devices.

BRIEF DESCRIPTION OF DRAWINGS

[0025]FIG. 1 is an enlarged view schematically showing an embodiment of an integrated sensor device.

[0026]FIG. 2 is a block diagram showing an embodiment of an integrated sensor device and a reading device of FIG. 1.

[0027]FIG. 3 is a view showing an embodiment of a measuring system.

[0028]FIG. 4 is an enlarged perspective view of a container in the measuring system of FIG. 3.

[0029]FIG. 5 is a flowchart showing operation of the measuring system of FIG. 3.

[0030]FIG. 6 is a view showing another embodiment of a measuring system.

[0031]FIG. 7 is a flowchart showing an operation of the measuring system of FIG. 6.

[0032]FIG. 8 is a view showing other embodiment of a measuring system.

[0033]FIG. 9 is a block diagram showing a procedure of electric power supply to the measuring system of FIG. 8.

[0034]FIG. 10 is a view showing a further embodiment of a measuring system.

BEST MODE FOR CARRYING OUT THE INVENTION

[0035]FIG. 1 is a enlarged view schematically showing construction of an integrated sensor device according to the present invention. The integrated sensor device is constructed into a single chip. The internal construction of the chip is parted into rectifier unit 1, regulator unit 2, CLK (clock) extraction unit 3, voltage sensing unit 4, modulator unit 5, detection (sensor) unit 6, control unit 7, A/D (analog/digital) converter unit 8, memory unit 9, and antenna unit 10 as to function block.

[0036] The sensor unit 6 may be constructed with various kinds of elements. For example, if the quantity of substance to be measured is hydrogen ion or pH, a known ion sensible field effect transistor (ISFET) can be used as the sensor unit. This has a gate constructed by a layer made of oxide and the like, in which a surface potential varies corresponding to a change of concentration of the substance to be measured. In this case, the sensor unit 6 has ISFET and reference electrode. It outputs a signal, into which the surface potential of the gate oxide layer of ISFET is converted by FET, as the measurement result of pH.

[0037] The sensor unit 6 may also have an organic membrane that has characteristics changed by the change of concentration of the substance to be measured and the conversion unit to convert the characteristic change to the electric signal. The sensor unit 6 can be used for measurement of value of resistance or capacitance by an arched type electrodes, measurement of value of capacitance by a parallel plate electrodes, or detection of change of weight by QCM (Quartz Crystal Microbalances), change of weight by SAW (Surface Acoustic Wave) device, change of weight by a cantilever, and the like. In this case the sensor unit 6 converts a physical quantity of gas concentration, stress, elastic coefficients and the like to an electric signal and outputs the signal as the measurement result.

[0038] The control unit 7 processes the signal showing the measurement result and also corrects the measurement result (for example, correction for calibration). Information required for correction (hereinafter, “correction information”) is stored in the memory unit 9. For example, information on zero point of each sensor device, measuring range (span), temperature characteristics and the like is stored. Based on the information of zero point, span and the like, the measurement data can be converted correspondingly to characteristics of the individual sensor. In addition, if a thermal or temperature sensor is also integrated or arranged outside, then it is possible to correct the temperature information due to the temperature characteristic of the individual sensor. The correction information includes a program for the signal processing in addition to the information of span. The control unit 7 may corrects the measurement result according to the program.

[0039] When a plurality of integrated sensor devices are used simultaneously, a sensor unit may be formed by different element in each device . In the case, ID (Identification) information to identify the integrated sensor device is stored in the memory unit 9. The ID information is transmitted to an outside device (for example, a reading device as mentioned later) together with the measurement result. The outside device can read the ID information to identify the measurement result transmitted from the integrated sensor device itself or the sensor device. Also, it is possible to prevent the outside device from reading the wrong data and information with no relation to the measurement result. The use of such ID information can advance the reliability of the measurement.

[0040] The antenna unit 10 transmits the measurement result to the outside device and also receive an energy supplied by microwaves from outside. The energy supplied through the antenna unit 10 is converted to electric current, voltage or clock signal necessary to operate each unit of the integrated sensor device by the rectifier unit 1, the regulator unit 2, the CLK extraction unit 3 and the voltage sensing unit 4, respectively.

[0041]FIG. 2 is a block diagram showing a construction of the integrated sensor device and the reading device of FIG. l. The integrated sensor device A and the reading device B transmit and receive the measurement result or energy with each other.

[0042] The function of the integrated sensor device A will be explained below.

[0043] The sensor unit 6 outputs the measurement result as a detection signal (analog signal) varying continuously. The detection signal is converted into digital signal by A/D converter unit 8.

[0044] The control unit 7 carry out necessary processing on the signal (the detection signal) representing the measurement result. If correction is necessary in processing, the control unit 7 refers to the correction information stored in the memory unit 9 and carries out the correction and so on. A correlation of before processing and after processing on the detection signal, that is, a relationship between input and output in the control unit 7 is not limited to be linear and it may be non-linear. Further, the measurement result may be corrected in the outside device that receives the detection signal other than the integrated sensor device.

[0045] The modulator unit 5 modulates carrier wave of the signal processed in the control unit 7. The modulated carrier wave is transmitted from the antenna unit 10 and is received by the antenna unit 16 of the reading device B.

[0046] Energy is supplied to the integrated sensor device A from the outside device (the reading device B in an example shown). An electromagnetic wave is used for transmission and reception of the measurement result and energy between the antenna unit 10 of the integrated sensor device A and the antenna unit 16 of the reading device B. The CLK extraction unit 3 extracts a clock signal from the received electromagnetic wave. The control unit 7 can operate based on the clock signal.

[0047] Energy supplied through the antenna unit 10 is rectified in the rectifier unit 1, and the voltage is regulated in the regulator unit 2. A direct current rectified in such way becomes power for actuating each unit. The voltage sensing unit 4 gives a signal representing that voltage reaches to predetermined level to the control unit 7 to permit the unit to operate only when it may operate.

[0048] The function of the reading device B will be explained below. The transmitted carrier wave from the integrated sensor device A is received at antenna unit 16 and is inputted to BPF (Band Pass Filter) unit 13. The BPF unit 13 may remove extra component from frequency component of the carrier wave. That is, only a predetermined frequency component including information of the processed measurement result is extracted. The carrier wave that extra frequency component has been removed is inputted to demodulation unit 14, in which the measurement result is taken out from the carrier wave with frequency oscillation of oscillator 12, and is indicated at display unit 15. The display unit 15 may also indicate the result of other signal processing on the detection signal. The frequency signal from the oscillator 12 is amplified in amplifier unit 11 and transmitted as electromagnetic wave or other microwave from the antenna unit 16 to the integrated sensor device A.

[0049]FIG. 3 shows an example of the measuring system according to the present invention. This measuring system includes take-up reel 17, supply reel 18, actuator 19, perforator 20, container 21-25, membrane seal 27 and transmitter-receiver unit 26.

[0050] An integrated sensor device (hereinafter “sensor chip”) is accommodated or stored in each container. As will be mentioned later, the sensor chip in the container is isolated from outside by a membrane seal 27. The membrane seal is opened by perforator 20 when using the sensor. The transmitter-receiver unit 26 receives the measurement result transmitted from the sensor chip in use (in container 23) and also sends energy to supply to the sensor chip.

[0051] The take-up reel 17 and the supply reel 18 are interlocked with each other by means for joining the containers into a belt with the membrane seal 27 (hereinafter “band of containers”). The band of sealed containers is wound up by the supply reel 18. On the other hand, the used band of containers is wound up by the take-up reel 17. These are rotated by a motor or the other drive source. The band of the containers is driven to run one by one container in a forward direction as shown by an arrow in FIG. 3. The perforator 20 is arranged to be reciprocally driven by the actuator 19 between the take-up reel 17 and the supply reel 18. The perforator 20 can open a lot of apertures in the membrane seal fixed on an upper surface of container 23 for use.

[0052]FIG. 4 is an enlarged perspective view of the containers in the measuring system of FIG. 3.

[0053] A container 28 is made by vacuum molding recess on soft plastic of vinyl chloride or the like. The membrane seal 27 consists of membrane of vinyl chloride or the like and it makes thermally contact bonding to the upper ends of the containers to seal the insides thereof. A sensor chip 29 is housed in the sealed container together with deoxidization material or moisture absorption materials (not shown).

[0054] In addition, materials of the container 28 and the membrane seal 27 may not be limited to vinyl chloride, but may be ones that can prevent air, moisture and gas to pass through. For example, they may be substituted by composite materials consisting of thin aluminum layer and macromolecular material, or aluminum foils. Also, one laminated by macromolecular materials having different characteristics is usable.

[0055]FIG. 5 is a flowchart showing operation of the measuring system of FIG. 3.

[0056] The time for replacement of the sensor is decided by a controller (ST1). If the controller decides that the sensor should be replaced, or “YES”, it gives instruction to operate to the motor and the like for driving the take-up reel 17. Then, the belt of the container is sent only by one stroke of container (ST2) to position the sealed container 23 under the perforator 20. Next, the controller gives instruction to operate to the actuator 19. Then, the perforator 20 turns down to bore an aperture in the membrane seal 27 of the container 23 (ST3). Then, a fresh air comes to contact with the sensor chip stored inside of the container. That is, the sensor chip becomes the state it can be used. Thus the characteristics of the outside environment is measured by the sensor chip (ST4).

[0057] By the way, there is a problem that generally an ion sensor using ion sensitive organic membrane does not have a stable characteristic when it start to be used if it has been kept in a dry atmosphere. Therefore, such sensor will be stabilized by dipping it in suitable solution over one night before it is used (that is called “conditioning”). Thus, when such sensor is used, it is preferable to fill the sensor chip container of the above embodiment with the solution for conditioning and to store the sensor chip therein. For example, if it is a “Na” ion sensor, it is kept in Nacl solution of 0.1N.

[0058] In this case the following means can be used instead of the perforator 20 in the system of FIG. 3. That is, as shown in FIG. 10, when the whole system is in fluid to be measured and the quantity of substance and the like is measured, a suitable holding member 63 holds tube 61 for suctioning fluid and tube 62 for discharging fluid in the vertical direction. The suction tube 61 is provided with pump 64, suction needle 61 n and discharge needle 62 n are fixed at lower end of each tube respectively, and the holding member 63 is moved reciprocally by the actuator 19. On the other hand, the sealed containers 24, 25 in the side of the supply reel 18 are filled with the conditioning solution L and holds the sensor chip therein.

[0059] In the system of FIG. 10, if it is decided that the sensor chip should be replaced as mentioned above, the take-up reel 17 is driven to position the container 23 storing an unused sensor chip just under the suction needle 61 n and the discharge needle 62 n. Then, the suction needle 61 n and the discharge needle 62 n are lowered by the actuator 19 to make apertures in the membrane seal 27 of the container 23. Further, the fluid to be measured is suctioned from the suction tube 61 by operating pump 64 to enter in the container 23 through the suction needle 61 n, then the conditioning solution L filled in the container runs through the discharge needle 62 n to the discharge tube 62, and is discharged from the upper end. In this way the container 23 is filled with the fluid to be measured and the sensor chip stored therein comes to contact with the fluid to be measured. That is, it is possible to replace the fluid in the container immediately to have the sensor chip set in the state it can used. The pump 64 may always operates or may be operated intermittently only when necessary.

[0060] In addition, it is preferable to arrange an suction inlet and a discharge outlet at remote position so that the drained fluid can not be suctioned again.

[0061] Though the above-mentioned measuring system is constructed to use only one sensor chip (in FIG. 3, a sensor chip stored in the container 23) for measurement, any sensor chip (for example, one in a prior container 22) can be used other than that sensor. That is, with arrangement of the transmitter-receiver 26 under the additional sensor chip, it will be possible to measure by means of two sensors. In this case, if a sensor in use should be replaced, another sensor can also be used so as to measure with simultaneous use of two sensors, and on decision of which degree is the difference between the measurement data of two sensors, the reliability (measurement data) of the sensor which has been used can be checked. According to a result of the check, the measurement with an old sensor is stopped at a predetermined time so that the sensor can be withdrawn.

[0062]FIG. 6 shows another measuring system. This measuring system has shutters 30, 31, stoppers 32, 33, storage device 34, and transmitter-receiver unit 35.

[0063] The storage device 34 is formed by a hollow box-shaped member or container in which a plurality of sensor chips 29 are lined up. The container 34 is inclined slightly against the horizontal. An inner wall of the container 34 is made by material having less friction with the sensor chip so that the sensor chip comes to slip by gravity at a slope. The inside of container 34 is sealed with screw lid 37, seal ring 38 and the shutters 30, 31 to maintain complete seal to outside. Further, absorbent 43 for removing oxygen or moisture is disposed in the container 34 so that unused sensor chip 29 is prevented from deterioration.

[0064] The shutters 30, 31 and the stoppers 32, 33 are arranged usually in closed position shown in FIG. 6, and the unused sensor chip 29 is hold in the container 34 sealed by the second shutter 31. When the sensor chip is replaced, the shutters 30, 31 and the stoppers 32, 33 slide in a direction as shown by an arrow. For example, the sliding can be realized by drive mechanism D such as solenoid. Seal is complete in place where the shutters 30, 31 in the container 34 and the first stopper 32 are driven. Accordingly, a fresh air can not enter into the container through such sliding portion.

[0065] Usually the sensor chip 29 is not accommodated in a pre-chamber 39 that is space sealed by the first shutter 30 and the second shutter 31, but the second shutter 31 is lifted when the sensor chip is replaced as mentioned later. On the other hand, as the first shutter 30 keeps in the lower position, a fresh air can not enter in the preservation chamber, thus the unused sensor chips in the preservation chamber can be kept for a long time.

[0066] A sensor chip 36 which is used outside of the container 34 is fixed to a predetermined position by the second stopper 33 and energy is supplied from the transmitter-receiver unit 35. A measurement result of the sensor chip 36 is transmitted from the transmitter-receiver unit 35. Further, sensor chip 41 used up is withdrawn to a collection bag 42.

[0067]FIG. 7 is a flowchart showing an operation procedure of the shutters 30, 31 and the stoppers 32, 33 in the measuring system of FIG. 6.

[0068] At first the controller decides the time for replacement of the sensor chip 36 in use (ST5). If “YES”, i. e., the time for replacement has come, then the second stopper 33 is dropped to discharge the used sensor chip 36 (ST6). The discharged sensor chip 41 comes to slide down to the collection bag 42 as shown in FIG. 6. Then, the second stopper 33 is lifted to the original position (ST7).

[0069] The second shutter 31 is lifted and new sensor chip 29′ at top slips down to the pre-chamber 39 from the container 34 (ST8). At this time, next and other sensor chips 29 are locked in the preservation container 34 by the first stopper 32. After the second shutter 31 drops to close (ST9), the first stopper 32 is lifted and when a first sensor chip 29 is stopped by the second shutter 31, the first stopper 32 drops to lock next sensor chip 29 (ST10).

[0070] Next, the first shutter 30 is lifted to move the sensor chip 29′ in the pre-chamber 39 to a position (36) for use(ST11). Then, the first shutter 30 is lowered to close the pre-chamber 39 (ST12). Here, it is preferable to remove fluid and moisture of the pre-chamber 39 exposed to outside.

[0071] As mentioned above, the sensor chips in the storage device are taken out one by one to the outside for use when the replacement of sensor chip is necessary.

[0072]FIG. 8 shows the other measuring system. This measuring system includes cartridge C, base 44 and actuator D.

[0073] The cartridge C consists of an upper case 45 and a lower case 46. A shaft 47 of the upper case 45 rotatably engages with bearing 48 of the lower case 46 and also with main shaft 49 as mentioned later. In use, the upper case 45 is combined with the lower case 46 into a unit.

[0074] The actuator D has motor 50, reduction gear 51 and main shaft 49 to be constructed. The reduction gear 51 adjusts number of rotation to transmit power of the motor 50 to the main shaft 49. The actuator is disposed in backside of the base 44. The main shaft 49 penetrates the base 44 to engage with the upper case 45 of the cartridge C. The power of motor 50 is transmitted via the main shaft 49 to the upper case 45.

[0075] A penetration aperture 52 is formed in the upper case 45. A plurality of small chambers 53 are arranged in the lower case 46. A sensor chip 54 is put in each of small chambers 53. It is preferable to put absorbent for absorbing humidity and oxygen together with the sensor chip in each small chamber. In measuring, the upper case 45 is combined with the lower case 46 to keep seal of each small chamber 53. The sensor chip 54 located just under the penetration aperture 52 is exposed in fresh air. The sensor chip exposed in fresh air transmits and receives the measurement result or energy between transmitter-receiver unit (not shown).

[0076] The upper case 45 engages with the main shaft 49 as mentioned above while the lower case 46 is fixed to the base 44. The lower case 46 can be attached to and detached from the base 44. The upper case 45 rotates by a predetermined angle by the motor 50 so that the sensor chip is located just under the penetration aperture 52. That is, this embodiment has mechanism to replace with next new sensor chip by turning the upper case 45 when a lifetime of the sensor chip is over.

[0077] Further, the cartridge C may engage detachably with the base 44. Therefore, an existing cartridge can be replaced by a new cartridge when lifetime of all sensors 54 put in the small chamber 53 is over.

[0078]FIG. 9 is a block diagram showing an electric power supply to the measuring system of FIG. 8.

[0079] Controller 58, driver 55 and reception circuit 57 are driven by electric power supplied from power source 56. The controller 58 checks lifetime of the sensor chip and gives instruction for operation to the driver 55 appropriately. The driver 55 controls operation of the actuator D of FIG. 8. More specifically, turn of the motor 50 is controlled so that the main shaft 49 of FIG. 8 rotates by a predetermined angle. As a method of control, potentiometers may be used for feedback control, or pulse motor may be used for open control. In addition, a receiver circuit 57 is a circuit for receiving the measurement result by the sensor chip 54 of FIG. 8 and for supplying energy to the sensor chip.

[0080] Though the embodiments of integrated sensor device and measuring system have been explained above, shape of the sensor chip, shape of the container, method of driving the actuator and so on are not limited to the embodiments.

[0081] For example, in the integrated sensor chip of FIG. 1, the sensor unit 6 may be constructed with a plurality of sensors. The sensors can measure pH and each ion of Na, K, Ca. In this case, since the reference electrode or the temperature sensor for compensation integrated in one chip can be used together and also can be produced all at once, it is more advantageous in cost than a plurality of integrated sensors that are made for each of different objects to be measured.

[0082] The integrated sensor device and the measuring system according to the present invention can used for measurement of various physical quantities, and in particular they are preferable for a manure monitor in hydroponics and the other environmental measurements. 

1. An integrated sensor device which is constructed into a single integrated circuit device comprising a detection unit that has an organic membrane, characteristics of which are changed through contact with gas or liquid containing substance to be measured, and a converter for converting the change of the characteristics to electric signal; a control unit for processing the signal representing the measurement result from the detection unit; and an antenna unit for transmitting the signal processed by the control unit to outside and for receiving energy necessary for the transmission and operations of the detection and control units from the outside.
 2. An integrated sensor device which is constructed into a single integrated circuit device comprising a detection unit that consists of an ion sensible FET device for measuring pH concentration in aqueous solution and a reference electrode; a thermal sensor for correcting measurement result of the detection unit; a control unit for processing a signal representing measurement result from the detection unit; and an antenna unit for transmitting the signal processed by the control unit to outside and for receiving energy necessary for the transmission and operations of the detection and control units from the outside.
 3. The integrated sensor device according to claim 1 or 2, wherein the control unit has memory for pre-storing correcting information to correct the measurement result of the detection unit, and in operation the control unit corrects the measurement result in accordance with the correcting information and transmits the corrected measurement result from the antenna unit.
 4. A reading device comprising: an antenna unit for receiving the measurement result transmitted from the integrated sensor device according to claim 1, 2, or 3 and for transmitting energy to be supplied to the integrated sensor device; and a display unit for displaying information on the measurement result received from the integrated sensor device through the antenna unit.
 5. A measuring system comprising: the integrated sensor device according to claim 1, 2, or 3; a container for storing a plurality of the integrated sensor devices; an actuator for actuating predetermined number of the integrated sensor devices stored in the container to be usable and for removing the deteriorated integrated sensor device; a controller for controlling operation of the actuator based on decision of whether performance of the integrated sensor device is deteriorated or predetermined time for use terminates; and an antenna unit for receiving the measurement result transmitted from the integrated sensor device in use and for transmitting energy to be supplied to the integrated sensor device.
 6. A measuring system comprising: the integrated sensor device according to claim 1, 2, or 3; a plurality of containers, each of which stores the integrated sensor device one by one; an actuator for actuating predetermined number of the integrated sensor devices stored in the container to be usable and for removing the deteriorated integrated sensor device; a controller for controlling operation of the actuator based on decision of whether performance of the integrated sensor device is deteriorated or predetermined time for use terminates; and an antenna unit for receiving the measurement result transmitted from the integrated sensor device in use and for transmitting energy to be supplied to the integrated sensor device.
 7. The measuring system according to claim 5 or 6, wherein the container has a seal to prevent invasion of gas or liquid from outside.
 8. The measuring system according to claim 7, wherein the container has absorbent inside to absorb substance that deteriorates the integrated sensor device.
 9. A measuring system comprising: the integrated sensor device according to claim 1, 2, or 3; a plurality of containers, each of which has a lid partly or wholly made by thin membrane, for sealing the integrated sensor device one by one inside together with gas or liquid to maintain the integrated sensor device in stability; an actuator for actuating predetermined number of the integrated sensor devices stored in the container to be usable and for removing the deteriorated integrated sensor device by opening an aperture in the thin membrane of the container; a controller for controlling operation of the actuator based on decision of whether performance of the integrated sensor device is deteriorated or predetermined time for use terminates; and an antenna unit for receiving the measurement result transmitted from the integrated sensor device in use and for transmitting energy to be supplied to the integrated sensor device.
 10. A container device comprising storage for storing a plurality of the integrated sensor devices according to claim 1, 2, or 3 in seal.
 11. A container device comprising storage for storing the integrated sensor device according to claim 1, 2, or 3 in seal one by one. 